ESSPY RD-101 1. Identification of the substance/mixture and of the company/undertaking Product identifier Trade name:ESSPY RD-101 CAS Number: 2426-08-6 Application of the substance / the preparation Reactive Diluent for Epoxy resins 2. Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: 2426-08-6 butyl glycidyl ether Xn R20/22-40-68; Xi R37-43 R10-52/53 Carc. Cat. 3, Muta. Cat. 3 H226; H341; H351; H302; H332; H317; H335; H412 71-36-3 butan-1-ol Xn R22; Xi R37/38-41 R10-67 H226; H318; H302; H315; H335+H336 3. Hazards identification Classification of the substance or mixture GHS02 Flame • H226 Flammable liquid and vapour. GHS08 Health hazard • H341 Suspected of causing genetic defects. • H351 Suspected of causing cancer. GHS07 • H302 Harmful if swallowed. • H317 May cause an allergic skin reaction. • H335 May cause respiratory irritation. • H333 May be harmful if inhaled. • H412 Harmful to aquatic life with long lasting effects. Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xn; Harmful • R20/22-40-68: Harmful by inhalation and if swallowed. Limited evidence of a carcinogenic effect. Possible risk of irreversible effects. Xi; Irritant • R37-43: Irritating to respiratory system. May cause sensitisation by skin contact. • R10-52/53: Flammable. Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Information concerning particular hazards for human and environment: The product has to be labelled due to the calculation procedure of international guidelines. Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon fromcompany and literature data. Label elements Labelling according to EU guidelines: The product has been classified and marked in accordance with directives on hazardous materials. Code letter and hazard designation of product: Xn Harmful Hazard-determining components of labelling: butylglycidyl ether Risk phrases: • 10 Flammable. • 20/22 Harmful by inhalation and if swallowed. • 37 Irritating to respiratory system. • 40 Limited evidence of a carcinogenic effect. • 43 May cause sensitisation by skin contact. • 68 Possible risk of irreversible effects. • 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: • 1/2 Keep locked up and out of the reach of children. • 29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. • 36/37/39 Wear suitable protective clothing, gloves and eye/face protection. • 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Classification system: NFPA ratings (scale 0 – 4) • Health = 1 • Fire = 2 • Reactivity = 0 HMIS-ratings (scale 0 – 4) • Health = *1 • Fire = 2 • Reactivity = 0 4. First aid measures General information: • Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after theaccident. After inhalation: • Supply fresh air and to be sure call for a doctor. • In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. DR After swallowing: Immediately call a doctor. 5. Firefighting measures Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. For safety reasons unsuitable extinguishing agents: Water with full jet Special hazards arising from the substance or mixture: No further relevant information available. Protective equipment: Mouth respiratory protective device. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures • Wear protective equipment. Keep unprotected persons away. Environmental precautions: • Do not allow product to reach sewage system or any water course. • Inform respective authorities in case of seepage into water course or sewage system. • Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: • Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). • Dispose contaminated material as waste according to item 13. • Ensure adequate ventilation. Reference to other sections • See Section 7 for information on safe handling. • See Section 8 for information on personal protection equipment. • See Section 13 for disposal information. 7. Handling and storage Handling: Precautions for safe handling • Store in cool, dry place in tightly closed receptacles. • Ensure good ventilation/exhaustion at the workplace. • Prevent formation of aerosols. Information about protection against explosions and fires: • Use explosion-proof apparatus / fittings and spark-proof tools. • Keep ignition sources away – Do not smoke. • Protect against electrostatic charges. Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: • Store under lock and key and out of the reach of children. • Keep receptacle tightly sealed. Specific end use(s) No further relevant information available. 8. Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: 2426-08-6 butyl glycidyl ether PEL REL TLV 270 mg/m³, 50 ppm Short-term value: C 30* mg/m³, C 5.6* ppm *15-min 16 mg/m³, 3 ppm Skin; SEN 71-36-3 butan-1-ol PEL REL TLV 300 mg/m³, 100 ppm Short-term value: C 150 mg/m³, C 50 ppm Skin 61 mg/m³, 20 ppm Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands:Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. …
ESSPY RD-250 Identification of substance Product details Technical Data here Trade name: ESSPY RD-250 Application of the substance / the preparation Reactive diluent for epoxy resins Composition/Data on components Chemical characterization: CAS No. Description [068413-24-1] Cashew, nutshell liq., oligomeric reaction products with 1- chloro-2,3-epoxypropane Identification number(s) NLP Number: 500-210-7 Hazards identification Hazard description: Xi Irritant Information pertaining to particular dangers for man and environment: R 36/38 Irritating to eyes and skin. R 43 May cause sensitisation by skin contact. R 53 May cause long-term adverse effects in the aquatic environment. Classification system: NFPA ratings (scale 0 – 4) Health = 1 Fire = 1 Reactivity = 0 HMIS-ratings (scale 0 – 4) Health = 1 Fire = 1 Reactivity = 0 GHS label elements Warning H410 – Very toxic to aquatic life with long lasting effects. Warning H315 – Causes skin irritation. H319 – Causes serious eye irritation. H317 – May cause an allergic skin reaction. Prevention: P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response: P302+P352 IF ON SKIN: Wash with plenty of soap and water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. P321 Specific treatment (see on this label). P332+P313 If skin irritation occurs: Get medical advice/attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362 Take off contaminated clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P391 Collect spillage. Disposal: P501 Dispose of contents/container in accordance with local/regional/national/international regulations. First aid measures After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing: If symptoms persist consult doctor. Fire fighting measures Suitable extinguishing agents: Use fire fighting measures that suit the environment. Protective equipment: No special measures required. Accidental release measures Person-related safety precautions: Not required. Measures for environmental protection: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Handling and storage Handling: Information for safe handling: No special measures required. Information about protection against explosions and fires: No special measures required. Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Do not store together with oxidizing and acidic materials. Further information about storage conditions: Keep receptacle tightly sealed. Exposure controls and personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: Not required. Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Breathing equipment: Not required. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Penetration time of glove material The exactbreak through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles Physical and chemical properties General Information Form: Liquid Color: Yellow Odor: Mild Change in condition Melting point/Melting range: Undetermined. Boiling point/Boiling range: 305°C (581°F) Flash point: 260°C (500°F) Danger of explosion: Product does not present an explosion hazard. Vapor pressure at 20°C (68°F):<8 hPa (<6 mm Hg) Density at 20°C (68°F): 0.98 – 1.02 g/cm³ Solubility in / Miscibility with Water: Insoluble. Viscosity: Dynamic at 25°C (77°F): 30 – 70 mPas Stability and reactivity Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Materials to be avoided: Strong Oxidising agents, Strong Alkali, Strong Bases, Amines Dangerous reactions Reacts with epoxy functional compounds with exothermic reaction liberation of fumes. Reacts with acids, alkalis and oxidizing agents. Dangerous products of decomposition: No dangerous decomposition products known. Toxicological information Acute toxicity: Primary irritant effect: on the skin: Irritant to skin and mucous membranes. on the eye: Irritating effect. Sensitization: Sensitization possible through skin contact. Ecological information General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Disposal considerations Product: Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. Uncleanedpackagings: Recommendation: Disposal must be made according to official regulations. Transport information DOT regulations: Hazard class: 9 Identification number: UN3082 Packing group: III Proper shipping name (technical name): ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Cashew, nutshell liq., oligomeric reaction products with 1- chloro-2,3-epoxypropane) Label 9 Land transport ADR/RID (cross-border): ADR/RID class: 9 …
ESSPY RD-700 Identification: Product identifier Trade name:ESSPY RD-700 CAS Number:2210-79-9 Relevant identified uses of the substance or mixture and uses advised against Sector of Use SU3 Industrial uses: Uses of substances as such or in preparations at industrial sites Application of the substance / the preparation Epoxy Reactive Diluents Details of the supplier of the safety data sheet Hazard(s) identification Classification of the substance or mixture GHS08 Health hazard H341 Suspected of causing genetic defects. GHS07 H315 Causes skin irritation. H317 May cause an allergic skin reaction. Classification according to Directive 67/548/EEC or Directive 1999/45/EC Xn; Harmful R68: Possible risk of irreversible effects. Xi; Irritant R38-43: Irritating to skin. May cause sensitisation by skin contact. N; Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Muta. Cat. 2 Label elements Labelling according to EU guidelines: The product has been classified and marked in accordance with directives on hazardous materials. Code letter and hazard designation of product: Mut a Cat. 2 Xn Harmful N Dangerous for the environment Risk phrases: 38 Irritating to skin. 43 May cause sensitisation by skin contact. 68 Possible risk of irreversible effects. 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: 2 Keep out of the reach of children. 36/37 Wear suitable protective clothing and gloves. 61 Avoid release to the environment. Refer to special instructions/safety data sheets. Classification system: NFPA ratings (scale 0 – 4) Health = 1 Fire = 0 Reactivity = 0 HMIS-ratings (scale 0 – 4) Health = 1 Fire = 0 Reactivity = 0 Other hazards Results of PBT and vPvB assessment PBT: Not applicable. vPvB: Not applicable. Composition/information on ingredients Chemical characterization: Substances CAS No. Description [CAS no: 2210-79-9] 2.3-epoxypropyl o-tolyl ether 100% Identification number(s) EC number: 218-645-3 Index number: 603-056-00-X SVHC Does not fall under SVHC substance First-aid measures Description of first aid measures After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. Information for doctor: Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture No further relevant information available. Advice for firefighters Fire fighters to wear self-contained breathing apparatus and suitable protective clothing if risk of exposure to vapor or products of combustion. Protective equipment: Wear self-contained respiratory protective device. Accidental release measures Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. Environmental precautions: Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Dispose contaminated material as waste according to item 13. Reference to other sections: See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Handling and storage Handling: Precautions for safe handling Directions for Safe Handling: Avoid inhalation. Do not get in eyes, on skin, on clothing. Avoid prolonged or repeated exposure. Keep away from heat and direct sunlight. Information about protection against explosions and fires: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. Keep receptacle tightly sealed. Specific end use(s) Reactive diluent for epoxy resins Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: Not required. Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the skin. Avoid contact with the eyes and skin. Breathing equipment: Not required. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemicalmixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation. Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Not required. Physical and chemical properties Information on basic physical and chemical properties General Information Form: Liquid Color: Colorless Odor: Characteristic Change in condition Boiling point/Boiling range: 240-245 °C (464-473 °F) Flash point:>120 °C (>248 °F) Danger of explosion: Product does not present an explosion hazard. Density at 20 °C (68 °F): 1.079 g/cm³ (9.004 lbs/gal) Solubility in / Miscibility with Water at 20 °C (68 °F): not miscible Viscosity: Dynamic: 5-10 cPs @25 Deg C Other information: No further relevant information available. Stability and …
ESSPY – AD/N61 Product and Company Identification Product Identification Recommended use of the chemical and restriction on use Recommended use* : Low Foam Surfactant Suitable for use in industrial sector : Chemical Industry The ‘recommended use’ identified for this product is provided solely to comply with a US Federal requirement and is not part of the seller’s published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the sellers sales agreement Hazard identification According to regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 GHS Classification Physical Hazards: Causes eye irritation. May Cause skin irritation May cause respiratory track irritation. May be harmful if swallowed. Health Hazards: No health hazards according to OSHA/GHS criteria Environmental Hazards: No environmental hazards according to OSHA/GHS Criteria. GHS label Elements, including precautionary statements Pictogram: Signal word: Danger Hazard Statements: H315 : Causes skin irritation Precautionary Statements (Prevention): P280 : Wear protective gloves P273 : Avoid release to the environment. P264 : Wash with plenty of water and soap thoroughly after handling. Precautionary Statement (Response): P303 + P352 : If on skin (or hair): Wash with plenty of soap and water. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P362 + P364 : Take off contaminated clothing and wash before reuse. Precautionary Statements (Disposal): P501 : Dispose of contents/ container to hazardous or special waste collection point. Hazards not otherwise classified Labeling of special preparations (GHS): The following percentage of the mixture consists of the component (s) with unknown hazards regarding the acute toxicity: 100% dermal. The following percentage of the mixture consists of the component (s) with unknown hazards regarding the acute toxicity: 100% inhalation – vapour. The following percentage of the mixture consists of the component (s) with unknown hazards regarding the acute toxicity: 100% inhalation – mist. According to regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Emergency Overview CAUTION: May cause eye, skin and respiratory tract irritation. Ingestion may cause Gastric disturbances. Use with local exhaust ventilation. Wear a NIOSH – certified (or equivalent) organic vapour/ particular respirator. Wear NIOSH – certified chemical goggles. Wear protective clothing. Wear chemical resistant protective gloves. Eye wash fountains and safety showers must be easily accessible. NO PARTICULAR HAZARD KNOWN. Composition/Information on Ingredients According to regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 According to regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 CompositionCAS Number EO/ PO Block Copolymer 9003 – 11-6 FIRST – AID MEASURES Descriptive first aid measures: General advise: Remove contaminated clothing. Inhaled: If difficulties occur after vapours/ aerosol has been inhaled, move to fresh air and seek medical attention. Skin contact: Wash affected areas thoroughly with soap and water. Remove contaminated clothing. If irritation develops, seek medical attention. Eye contact: Rinse eyes for at least 15 minutes under running water with eyelids wide open. Ingestion: Rinse mouth and then drink plenty of water. Most important symptoms and effects, both acute and delayed. Symptoms: No significant symptoms are expected due to the non – classification of the product. Indication of any immediate medical attention and special treatment needed Note to Physician: Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. FIRE – FIGHTING MEASURES Suitable Extinguishing Media: Water spray, dry Powder or foam. Unsuitable Extinguishing Media: Water jet Protective Equipment for Fire – fighting: Fire fighters should be equipped with self-contained breathing apparatus and turn out gear. Additional Information: Contaminated extinguishing water must be disposed ofin accordance with official regulations. ACCIDENTAL RELEASE MEASURES Personal Precautions Use personal protective equipment. Information regarding personal protective equipment see section 8. Environmental Precautions Do not discharge into drains/ surface water/ ground water. Methods and material for containment and cleaning -up Dispose of absorbed material in accordance with regulations. Small spill and leak: Dilute with water and mob up or absorb with absorbent material (e.g. sand, silica gel acid binder, general purpose binder, sawdust). Finish cleaning by spreading water on contaminated surface. Large spill and leak:Pick up with suitable adsorbent material or vacuum up spilled product. Place into suitable container for disposal. Finish cleaning by spreading water on contaminated surface. HANDLING AND STORAGE Precautions of safe handling No special measures are necessary provided the product is handled in accordance with good industrial hygiene and safety practice. Protection against fire an explosion: No special precautions are necessary. Conditions for safe storage, including any incompatibilities Segregate from acids and bases. Segregate from oxidising agents. Other Information on storage conditions: Keep container tightly closed and dry. Store in a cool and well-ventilated area. EXPOSURE CONTROLS AND PERSONAL PROTECTION Advise on system design: Provide local exhaust ventilation to control vapours/ mists. Personal Protective Equipment Respiratory Protection: Wear respiratory protection if ventilation is inadequate. Breathing protection if breathable aerosols/ dust are formed. Hand protection: Chemical resistance protective gloves. Eye protection: Tightly fitting safety goggles (chemical goggles) and face shield. General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is recommended. Wear protective clothing as necessary to minimise contact. PHYSICAL AND CHEMICAL PROPERTIES: Form : Liquid Odour : Slight Characteristic Odour threshold : N/D Colour : Colurless to pale yellow pH (2.5% aq.) : 6.50 – 7.50 Solubility : Insoluble in water Boiling point : >200 deg. C Vapour pressure : N/D Auto ignition temperature : N/D Vapour Density (Air = 1) : N/D Freezing point : N/D Decomposition Temperature : N/D Flash Point : > 150oC Flammability : N/D STABILITY AND REACTIVITY Hazardous Reactions No hazardous reactions when stored and handled according to the instructions. The product is chemically stable. Decomposition Products Hazardous decomposition Products: No hazardous decomposition products if stored and handled as prescribed or indicated. Thermal Decomposition No data available. Corrosion of metals No corrosion effect on metals. Toxicological Information Primary …
ESSPY – AD/N90 Product and Company Identification Product Identification Recommended use of the chemical and restriction on use Recommended use* : Surfactant Suitable for use in industrial sector : Chemical Industry The ‘recommended use’ identified for this product is provided solely to comply with a US Federal requirement and is not part of the seller’s published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the sellers sales agreement Hazard identification According to regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 GHS Classification Physical Hazards: Causes eye irritation. May Cause skin irritation May cause respiratory track irritation. May be harmful if swallowed. Health Hazards: No health hazards according to OSHA/GHS criteria Environmental Hazards: No environmental hazards according to OSHA/GHS Criteria. GHS label Elements, including precautionary statements Pictogram: Signal word: Danger Hazard Statements: H315 : Causes skin irritation Precautionary Statements (Prevention): P280 : Wear protective gloves P273 : Avoid release to the environment. P264 : Wash with plenty of water and soap thoroughly after handling. Precautionary Statement (Response): P303 + P352 : If on skin (or hair): Wash with plenty of soap and water. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P362 + P364 : Take off contaminated clothing and wash before reuse. Precautionary Statements (Disposal): P501 : Dispose of contents/ container to hazardous or special waste collection point. Hazards not otherwise classified Labeling of special preparations (GHS): The following percentage of the mixture consists of the component (s) with unknown hazards regarding the acute toxicity: 100% dermal. The following percentage of the mixture consists of the component (s) with unknown hazards regarding the acute toxicity: 100% inhalation – vapour. The following percentage of the mixture consists of the component (s) with unknown hazards regarding the acute toxicity: 100% inhalation – mist. According to regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Emergency Overview CAUTION: May cause eye, skin and respiratory tract irritation. Ingestion may cause Gastric disturbances. Use with local exhaust ventilation. Wear a NIOSH – certified (or equivalent) organic vapour/ particular respirator. Wear NIOSH – certified chemical goggles. Wear protective clothing. Wear chemical resistant protective gloves. Eye wash fountains and safety showers must be easily accessible. NO PARTICULAR HAZARD KNOWN. Composition/Information on Ingredients According to regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 According to regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 CompositionCAS Number Polyalkylene Glycol Mono Butyl Ether 9038-95-3 FIRST – AID MEASURES Descriptive first aid measures: General advise: Remove contaminated clothing. Inhaled: If difficulties occur after vapours/ aerosol has been inhaled, move to fresh air and seek medical attention. Skin contact: Wash affected areas thoroughly with soap and water. Remove contaminated clothing. If irritation develops, seek medical attention. Eye contact: Rinse eyes for at least 15 minutes under running water with eyelids wide open. Ingestion: Rinse mouth and then drink plenty of water. Most important symptoms and effects, both acute and delayed. Symptoms: No significant symptoms are expected due to the non – classification of the product. Indication of any immediate medical attention and special treatment needed Note to Physician: Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. FIRE – FIGHTING MEASURES Suitable Extinguishing Media: Water spray, dry Powder or foam. Unsuitable Extinguishing Media: Water jet Protective Equipment for Fire – fighting: Fire fighters should be equipped with self-contained breathing apparatus and turn out gear. Additional Information: Contaminated extinguishing water must be disposed ofin accordance with official regulations. ACCIDENTAL RELEASE MEASURES Personal Precautions Use personal protective equipment. Information regarding personal protective equipment see section 8. Environmental Precautions Do not discharge into drains/ surface water/ ground water. Methods and material for containment and cleaning -up Dispose of absorbed material in accordance with regulations. Small spill and leak: Dilute with water and mob up or absorb with absorbent material (e.g. sand, silica gel acid binder, general purpose binder, sawdust). Finish cleaning by spreading water on contaminated surface. Large spill and leak:Pick up with suitable adsorbent material or vacuum up spilled product. Place into suitable container for disposal. Finish cleaning by spreading water on contaminated surface. HANDLING AND STORAGE Precautions of safe handling No special measures are necessary provided the product is handled in accordance with good industrial hygiene and safety practice. Protection against fire an explosion: No special precautions are necessary. Conditions for safe storage, including any incompatibilities Segregate from acids and bases. Segregate from oxidising agents. Other Information on storage conditions: Keep container tightly closed and dry. Store in a cool and well-ventilated area. EXPOSURE CONTROLS AND PERSONAL PROTECTION Advise on system design: Provide local exhaust ventilation to control vapours/ mists. Personal Protective Equipment Respiratory Protection: Wear respiratory protection if ventilation is inadequate. Breathing protection if breathable aerosols/ dust are formed. Hand protection: Chemical resistance protective gloves. Eye protection: Tightly fitting safety goggles (chemical goggles) and face shield. General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is recommended. Wear protective clothing as necessary to minimise contact. PHYSICAL AND CHEMICAL PROPERTIES: Form : Liquid Odour : Slight Characteristic Odour threshold : N/D Colour : Colourless to Yellow Solubility : Soluble Boiling Point : > 200oC Vapour pressure : N/D Auto ignition temperature : N/D Vapour Density (Air = 1) : N/D Freezing point : N/D Decomposition Temperature : N/D Flash Point : > 150oC Flammability : N/D STABILITY AND REACTIVITY Hazardous Reactions No hazardous reactions when stored and handled according to the instructions. The product is chemically stable. Decomposition Products Hazardous decomposition Products: No hazardous decomposition products if stored and handled as prescribed or indicated. Thermal Decomposition No data available. Corrosion of metals No corrosion effect on metals. Toxicological Information Primary routes exposure: Routes of entry for solids and liquids are ingestion and inhalation, but …
ESSPY –AD/N55 Product and Company Identification Product Identification Product Name: ESSPY – AD/N55 Recommended use of the chemical and restriction on use Recommended use* : Defoamer Suitable for use in industrial sector : Chemical Industry The ‘recommended use’ identified for this product is provided solely to comply with a US Federal requirement and is not part of the seller’s published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the sellers sales agreement Hazard identification According to regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 GHS Classification Physical Hazards: Causes eye irritation. May Cause skin irritation May cause respiratory track irritation. May be harmful if swallowed. Health Hazards: No health hazards according to OSHA/GHS criteria Environmental Hazards: No environmental hazards according to OSHA/GHS Criteria. GHS label Elements, including precautionary statements Pictogram: Signal word: Danger Hazard Statements: H315 : Causes skin irritation Precautionary Statements (Prevention): P280 : Wear protective gloves P273 : Avoid release to the environment. P264 : Wash with plenty of water and soap thoroughly after handling. Precautionary Statement (Response): P303 + P352 : If on skin (or hair): Wash with plenty of soap and water. P332 + P313 : If skin irritation occurs: Get medical advice/ attention. P362 + P364 : Take off contaminated clothing and wash before reuse. Precautionary Statements (Disposal): P501 : Dispose of contents/ container to hazardous or special waste collection point. Hazards not otherwise classified Labeling of special preparations (GHS): The following percentage of the mixture consists of the component (s) with unknown hazards regarding the acute toxicity: 100% dermal. The following percentage of the mixture consists of the component (s) with unknown hazards regarding the acute toxicity: 100% inhalation – vapour. The following percentage of the mixture consists of the component (s) with unknown hazards regarding the acute toxicity: 100% inhalation – mist. According to regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Emergency Overview CAUTION: May cause eye, skin and respiratory tract irritation. Ingestion may cause Gastric disturbances. Use with local exhaust ventilation. Wear a NIOSH – certified (or equivalent) organic vapour/ particular respirator. Wear NIOSH – certified chemical goggles. Wear protective clothing. Wear chemical resistant protective gloves. Eye wash fountains and safety showers must be easily accessible. NO PARTICULAR HAZARD KNOWN. Composition/Information on Ingredients According to regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 According to regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200 Composition Fatty Alcohol Alkoxylate FIRST – AID MEASURES Descriptive first aid measures: General advise: Remove contaminated clothing. Inhaled: If difficulties occur after vapours/ aerosol has been inhaled, move to fresh air and seek medical attention. Skin contact: Wash affected areas thoroughly with soap and water. Remove contaminated clothing. If irritation develops, seek medical attention. Eye contact: Rinse eyes for at least 15 minutes under running water with eyelids wide open. Ingestion: Rinse mouth and then drink plenty of water. Most important symptoms and effects, both acute and delayed. Symptoms: No significant symptoms are expected due to the non – classification of the product. Indication of any immediate medical attention and special treatment needed Note to Physician: Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. FIRE – FIGHTING MEASURES Suitable Extinguishing Media: Water spray, dry Powder or foam. Unsuitable Extinguishing Media: Water jet Protective Equipment for Fire – fighting: Fire fighters should be equipped with self-contained breathing apparatus and turn out gear. Additional Information: Contaminated extinguishing water must be disposed ofin accordance with official regulations. ACCIDENTAL RELEASE MEASURES Personal Precautions Use personal protective equipment. Information regarding personal protective equipment see section 8. Environmental Precautions Do not discharge into drains/ surface water/ ground water. Methods and material for containment and cleaning -up Dispose of absorbed material in accordance with regulations. Small spill and leak: Dilute with water and mob up or absorb with absorbent material (e.g. sand, silica gel acid binder, general purpose binder, sawdust). Finish cleaning by spreading water on contaminated surface. Large spill and leak:Pick up with suitable adsorbent material or vacuum up spilled product. Place into suitable container for disposal. Finish cleaning by spreading water on contaminated surface.. HANDLING AND STORAGE Precautions of safe handling No special measures are necessary provided the product is handled in accordance with good industrial hygiene and safety practice. Protection against fire an explosion: No special precautions are necessary. Conditions for safe storage, including any incompatibilities Segregate from acids and bases. Segregate from oxidising agents. Other Information on storage conditions: Keep container tightly closed and dry. Store in a cool and well-ventilated area. EXPOSURE CONTROLS AND PERSONAL PROTECTION Advise on system design: Provide local exhaust ventilation to control vapours/ mists. Personal Protective Equipment Respiratory Protection: Wear respiratory protection if ventilation is inadequate. Breathing protection if breathable aerosols/ dust are formed. Hand protection: Chemical resistance protective gloves. Eye protection: Tightly fitting safety goggles (chemical goggles) and face shield. General safety and hygiene measures: Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is recommended. Wear protective clothing as necessary to minimise contact. PHYSICAL AND CHEMICAL PROPERTIES: Form : Liquid Odour : Slight Characteristic Odour threshold : N/D Colour : Yellow to yellowish brown pH 1 % in 10:6 ( IPA: Water ) : 6.00 – 8.00 Boiling Point : > 100oC Vapour pressure : N/D Auto ignition temperature : N/D Vapour Density (Air = 1) : N/D Freezing point : N/D Decomposition Temperature : N/D Flash Point : > 150oC Flammability : N/D STABILITY AND REACTIVITY Hazardous Reactions No hazardous reactions when stored and handled according to the instructions. The product is chemically stable. Decomposition Products Hazardous decomposition Products: No hazardous decomposition products if stored and handled as prescribed or indicated. Thermal Decomposition No data available. Corrosion of metals No corrosion effect on metals. Toxicological Information Primary routes …
ESSPY RD-167 ESSPY RD-167 Description: ESSPY RD-167 is a clear low viscosity liquid, aromatic mono epoxide reactive diluent based on phenol. ESSPY RD-167 is compatible with all types of epoxy resin in any proportion Resins diluted with ESSPY RD-167 can be suitably cured by epoxy curing agents for variety of applications. Higher proportion of ESSPY RD-167 imparts flexibility in cured system and hence affects glass transition temperature significantly. Chemical structure: Advantages: Reduces viscosity while maintaining most cured properties. Improves wetting and process ability. Practically no reduction of hardness. High resistance to solvents and ammonia. Low volatile. Applications: Civil engineering and flooring. Glass fiber lamination. Casting and potting of electrical and electronics components. Adhesives and tooling systems. Solvents free as well as solvent containing coatings. Typical Data: Property Unit Test Method Values Appearance — Visual Appearance Clear Liquid Color GS ASTM D 1544 Max. 2 Epoxy Value Eq/Kg. ASTM D 1652 5.90 – 6.30 Epoxy Equivalent Weight (EEW) g/eq ASTM D 1652 159 – 170 Viscosity at 250C mPas ASTM D 2196 6 – 8 Hydrolysable Chlorine % ASTM D 1726 Max. 0.20 Storage And Handling: ESSPY RD-167 should be stored in cool and dry place, preferably in the sealed container and should not be exposed to direct sunlight. ESSPY RD-167 has a shelf life of two years if stored in its original container between 2 – 40°C away from humidity and excessive heat. ESSPY RD-167 may causes pronounced skin irritation therefore rubber gloves, eye protection creams and breathing mask are recommended. Please refer MSDS for detail safety instruction. Note: All recommendations for use of our products, whether given by us in writing, verbally are to be implied, from the results of tests carried out by us, based on the current state of our knowledge. Although the information contained in this sheet is accurate to the best of our knowledge, no liability can be accepted in respect of such information and no warranty or conditions are intended in respect of the products described, as the conditions of application are beyond our control.
ESSPY COT-100 Identification of substance1 Identification of substance: PRODUTS DETAILS: Trade name: ESSPY COT-100 Article number: reaction product: bisphenol-A-(epichlorhydrin) epoxy resin. Application of the substance /the preparation Epoxy resin Composition/Data on components: Chemical characterization: CAS No. Description 25068-38-6 [Reaction product: bisphenol-A-(epichlorhydrin) epoxy resin. Hazards identification Hazard description: Xi Irritant N Dangerous for the environment Information pertaining to particular dangers for man and environment: R 36/38 Irritating to eyes and skin. R 43 May cause sensitisation by skin contact. R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Contains epoxy constituents. See information supplied by the manufacturer. Classification system: NFPA ratings (scale 0 – 4) Health = 1 Fire = 0 Reactivity = 0 HMIS-Ratings (scale 0 – 4) Health = 1 Fire = 0 Reactivity = 0 GHS label element: Warning H315 – Causes skin irritation. H319 – Causes serious eye irritation. H317 – May cause an allergic skin reaction. H411 – Toxic to aquatic life with long lasting effects. Prevention: P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. Response: P302+P352 IF ON SKIN: Wash with plenty of soap and water. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment (see on this label). P332+P313 If skin irritation occurs: Get medical advice/attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P362 Take off contaminated clothing and wash before reuse. P363 Wash contaminated clothing before reuse. P391 Collect spillage. Disposal: P501 Dispose of contents/container in accordance with local/regional/national/international regulations. First aid measures After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing: If symptoms persist consult doctor. Fire fighting measures Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. For safety reasons unsuitable extinguishing agents: Water spray Extinguishing powder Protective equipment: Wear self-contained respiatory protective device. Accidental release measures Person-related safety precautions: Mount respiratory protective device. Remove persons from danger area. Measures for environmental protection: Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Measures for cleaning/collecting: Large spills: In a clean area, dike and recover for reuse. Keep out of sewars and waterways. Dispose of contaminated material. Small spills: Use absorbent pad or mix with absorbent material and dispose Handling and storage Handling: Information for safe handling: Store in cool, dry place in tightly closed receptacles. Information about protection against explosions and fires: Protect from heat. Storage: Requirements to be met by storerooms and receptacles: Store only in the original receptacle. Store in a cool location. Information about storage in one common storage facility: Do not store together with oxidizing and acidic materials. Store away from oxidizing agents. Further information about storage conditions: Keep receptacle tightly sealed. Exposure controls and personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: Not required. Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Breathing equipment: Not required. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves: The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Penetration time of glove material: The exact break through time has to be found out by the manufacturer of the protective gloves and has to be Observed. Eye protection: Tightly sealed goggles Physical and chemical properties General Information: Form: Liquid Color: Colorless Odor: Characteristic Change in condition Boiling point/Boiling range: >200°C (>392°F) Flash point: >200°C (>392°F) Danger of explosion: Product does not present an explosion hazard. Density at 25°C (77°F): 1.15 – 1.20 g/cm³ Solubility in / Miscibility with Water: Insoluble. pH-value: Neutral Viscosity: Dynamic at 25°C (77°F): 10.000 – 12.000 mPas (Brookfield DV II) Stability and reactivity Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Materials to be avoided: Strong Oxidising agents, Strong Alkali, Strong Bases, Amines Dangerous reactions Reacts with amines with exothermic reaction liberating heat and fumes Dangerous products of decomposition: Carbon monoxide and carbon dioxide Toxicological information Acute toxicity: Primary irritant effect: On the skin: Irritant to skin and mucous membranes. On the eye: Irritating effect. Sensitization: Sensitization possible through skin contact. Ecological information Ecotoxical effects: Remark: Toxic for fish General notes: Water hazard class 2 (Assessment …
ESSPY EXA-270 Identification PRODUTS DETAILS: Trade name: ESSPY EXA-270 Accelerator for epoxy resins. Industrial uses: uses of substances as such or in preparations at industrial sites accelerator Application of the substance /the preparationEpoxy resin Hazard(s) identification Classification of the substance or mixture GHS07 Acute Tox. 4 H302 Harmful if swallowed. Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2A H319 Causes serious eye irritation. Label elements GHS label elements The substance is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS07 Signal word Warning Hazard-determining components of labeling: 2,4,6-tris(dimethylaminomethyl)phenol Hazard statements H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. Precautionary statements P101 If medical advice is needed, have product container or label at hand. P102 Keep out of reach of children. P103 Read label before use. P280 Wear protective gloves. P280 Wear eye protection / face protection. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 Specific treatment (see on this label). P301+P312 If swallowed: Call a poison center/doctor if you feel unwell. P332+P313 If skin irritation occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P330 Rinse mouth. P302+P352 If on skin: Wash with plenty of water. P362+P364 Take off contaminated clothing and wash it before reuse. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Classification system: NFPA ratings (scale 0 – 4) Health = 3 Fire = 0 Reactivity = 0 HMIS-ratings (scale 0 – 4) Health = 3 Fire = 0 Reactivity = 0 Other hazards Results of PBT and vPvB assessment PBT: No data available vPvB: No data available Composition/information on ingredients Chemical characterization: Substances CAS No. Description [90-72-2] 2,4,6-tris(dimethylaminomethyl)phenol 95-100% Identification number(s) EC number: 202-013-9 Index number: 603-069-00-0 SVHC Does not fall under SVHC substance First-aid measures Description of first aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing: Immediately call a doctor. Drink copious amounts of water and provide fresh air. Immediately call a doctor. Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available. Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire. Advice for firefighters Fire fighters to wear self-contained breathing apparatus and suitable protective clothing if risk of exposure to vapour or products of combustion. Protective equipment: Wear self-contained respiratory protective device. Accidental release measures Personal precautions, protective equipment and emergency procedures Remove persons from danger area. Ensure adequate ventilation Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. Handling and storage Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about protection against explosions and fires: Protect from heat. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: Do not store together with reducing agents, heavy-metal compounds, acids and alkalis. Further information about storage conditions: Keep receptacle tightly sealed. Specific end use(s) Accelerator for epoxy resins. Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: Not required. Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. Eye protection: Tightly sealed goggles Body protection: Protective work clothing. …
ESSPY EXA-450 Identification of substance PRODUTS DETAILS: Trade name: ESSPY EXA-450 Application of the substance / the preparation Curing agent for epoxy resin Composition/Data on components Chemical characterization Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: 111-40-0 2, 2’-iminodiethylamine C, Xn; R 21/22-34-43 Danger: 3.2/1B Warning: 3.1.O/4, 3.1.D/4, 3.4.S/1 50-70% 80-05-7 bisphenol A Repr. Cat. 3; Xn, Xi; R 37-41-43-62-52 Danger: 3.3/1 Warning: 3.7/2; 3.4.S/1, 3.8/3 25-45% Hazards identification Hazard description: C Corrosive Information pertaining to particular dangers for man and environment: The product has to be labelled due to the calculation procedure of international guidelines. R 21/22 Harmful in contact with skin and if swallowed. R 34 Causes burns. R 37 Irritating to respiratory system. R 43 May cause sensitisation by skin contact. R 62 Possible risk of impaired fertility. R 52 Harmful to aquatic organisms. Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon From company and literature data. NFPA ratings (scale 0 – 4) 3 1 0 Health = 3 Fire = 1 Reactivity = 0 HMIS-ratings (scale 0 – 4) HEALTH FIRE REACTIVITY *3 1 0 Health = *3 Fire = 1 Reactivity = 0 GHS label elements Danger H314 – Causes severe skin burns and eye damage. Warning H361 – Suspected of damaging fertility or the unborn child. Warning H302 – Harmful if swallowed. H312 – Harmful in contact with skin. H317 – May cause an allergic skin reaction. H335 – May cause respiratory irritation. H402 – Harmful to aquatic life. Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P270 Do no eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. Response: P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER or doctor/physician. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P321 Specific treatment (see on this label). P322 Specific measures (see on this label). P330 Rinse mouth. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse. Storage: P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Disposal: P501 Dispose of contents/container in accordance with local/regional/national/international regulations. First aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Immediately call a doctor. Drink copious amounts of water and provide fresh air. Immediately call a doctor. Fire fighting measures Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Protective equipment: Wear fully protective suit. Accidental release measures Person-related safety precautions: Wear protective equipment. Keep unprotected persons away. Measures for environmental protection: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation. Handling and storage Handling: Information for safe handling: Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about protection against explosions and fires: No special measures required. Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep receptacle tightly sealed. Exposure controls and personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: 111-40-0 2,2′-iminodiethylamine REL TLV 4 mg/m³, 1 ppm Skin 4.2 mg/m³, 1 ppm Skin Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on …