1. Identification

PRODUTS DETAILS:

• Trade name: ESSPY EXA-270

Accelerator for epoxy resins.

Industrial uses: uses of substances as such or in preparations at industrial sites accelerator

Application of the substance /the preparationEpoxy resin

  1. Hazard(s) identification

Classification of the substance or mixture

GHS07

Acute Tox. 4 H302 Harmful if swallowed.

Skin Irrit. 2 H315 Causes skin irritation.

Eye Irrit. 2A H319 Causes serious eye irritation.

Label elements

GHS label elements The substance is classified and labeled according to the Globally Harmonized

System (GHS).

Hazard pictograms

GHS07

Signal word Warning

Hazard-determining components of labeling:

• 2,4,6-tris(dimethylaminomethyl)phenol

Hazard statements

• H302 Harmful if swallowed.

• H315 Causes skin irritation.

• H319 Causes serious eye irritation.

Precautionary statements

• P101 If medical advice is needed, have product container or label at hand.

• P102 Keep out of reach of children.

• P103 Read label before use.

• P280 Wear protective gloves.

• P280 Wear eye protection / face protection.

• P264 Wash thoroughly after handling.

• P270 Do not eat, drink or smoke when using this product.

• P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

• P321 Specific treatment (see on this label).

• P301+P312 If swallowed: Call a poison center/doctor if you feel unwell.

• P332+P313 If skin irritation occurs: Get medical advice/attention.

• P337+P313 If eye irritation persists: Get medical advice/attention.

• P330 Rinse mouth.

• P302+P352 If on skin: Wash with plenty of water.

• P362+P364 Take off contaminated clothing and wash it before reuse.

• P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

Classification system:

NFPA ratings (scale 0 – 4)

Health = 3

Fire = 0

Reactivity = 0

HMIS-ratings (scale 0 – 4)

Health = 3

Fire = 0

Reactivity = 0

Other hazards

Results of PBT and vPvB assessment

PBT: No data available

vPvB: No data available

 

  1. Composition/information on ingredients

Chemical characterization: Substances

CAS No. Description

[90-72-2] 2,4,6-tris(dimethylaminomethyl)phenol 95-100%

Identification number(s)

EC number: 202-013-9

Index number: 603-069-00-0

SVHC Does not fall under SVHC substance

 

  1. First-aid measures

Description of first aid measures

General information:

Immediately remove any clothing soiled by the product.

Symptoms of poisoning may even occur after several hours; therefore medical observation for at

least 48 hours after the

accident.

After inhalation: In case of unconsciousness place patient stably in side position for transportation.

After skin contact: Immediately wash with water and soap and rinse thoroughly.

After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist,

consult a doctor.

After swallowing:

• Immediately call a doctor.

• Drink copious amounts of water and provide fresh air. Immediately call a doctor.

Most important symptoms and effects, both acute and delayed No further relevant information

available.

Indication of any immediate medical attention and special treatment needed No further relevant

information available.

 

  1. Fire-fighting measures

Extinguishing media

Suitable extinguishing agents:

CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant

foam.

Special hazards arising from the substance or mixture

Formation of toxic gases is possible during heating or in case of fire.

Advice for firefighters

• Fire fighters to wear self-contained breathing apparatus and suitable protective clothing if

risk of exposure to vapour or products of combustion.

Protective equipment: Wear self-contained respiratory protective device.

 

  1. Accidental release measures

Personal precautions, protective equipment and emergency procedures

• Remove persons from danger area.

• Ensure adequate ventilation

• Wear protective equipment. Keep unprotected persons away.

Environmental precautions: Do not allow to enter sewers/ surface or ground water.

Methods and material for containment and cleaning up:

• Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders,

sawdust).

• Use neutralizing agent.

• Dispose contaminated material as waste according to item 13.

• Ensure adequate ventilation.

Reference to other sections

• See Section 7 for information on safe handling.

• See Section 8 for information on personal protection equipment.

• See Section 13 for disposal information.

 

  1. Handling and storage

Precautions for safe handling

• Ensure good ventilation/exhaustion at the workplace.

• Prevent formation of aerosols.

Information about protection against explosions and fires: Protect from heat.

Conditions for safe storage, including any incompatibilities

Storage:

Requirements to be met by storerooms and receptacles: Store in a cool location.

Information about storage in one common storage facility:

• Do not store together with reducing agents, heavy-metal compounds, acids and alkalis.

Further information about storage conditions: Keep receptacle tightly sealed.

Specific end use(s) Accelerator for epoxy resins.

 

  1. Exposure controls/personal protection

Additional information about design of technical systems: No further data; see item 7.

Control parameters

Components with limit values that require monitoring at the workplace: Not required.

Additional information: The lists that were valid during the creation were used as basis.

Exposure controls

Personal protective equipment:

General protective and hygienic measures:

• Keep away from foodstuffs, beverages and feed.

• Immediately remove all soiled and contaminated clothing.

• Wash hands before breaks and at the end of work.

• Avoid contact with the eyes and skin.

Breathing equipment:

• In case of brief exposure or low pollution use respiratory filter device. In case of intensive or

longer exposure use respiratory protective device that is independent of circulating air.

Protection of hands: Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the

preparation.

Due to missing tests no recommendation to the glove material can be given for the product/ the

preparation/ the chemical mixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the

degradation

Material of gloves

The selection of the suitable gloves does not only depend on the material, but also on further marks

of quality and varies from manufacturer to manufacturer.

Penetration time of glove material

• The exact break through time has to be found out by the manufacturer of the protective

gloves and has to be observed.

Eye protection:

• Tightly sealed goggles

Body protection: Protective work clothing.

 

  1. Physical and chemical properties

Information on basic physical and chemical properties

General Information

Form: Liquid

Color: Yellow

Odor: Characteristic

pH-value: Alkaline

Change in condition

Boiling point/Boiling range: > 150 °C (> 302 °F)

Flash point: 148 °C (298 °F) (Closed cup)

Flammability (solid, gaseous): Not applicable.

Auto igniting: Product is not selfigniting.

Danger of explosion: Product does not present an explosion hazard.

Vapor pressure at 20 °C (68 °F): 0.001 hPa

Density at 20 °C (68 °F): 0.98 g/cm³ (8.178 lbs/gal)

Solubility in / Miscibility with

Water: Fully miscible.

Partition coefficient (n-octanol/water): No data available

Viscosity:

Dynamic at 25 °C (77 °F): 150 – 300 mPas (ASTM D 2196)

Organic solvents: 0.0 %

Other information No further relevant information available.

 

  1. Stability and reactivity

Reactivity

Chemical stability

Thermal decomposition / conditions to be avoided: No decomposition if used according to

specifications.

Possibility of hazardous reactions Reacts with epoxy functional compounds with exothermic

reaction liberation of fumes.

Conditions to avoid No further relevant information available.

Incompatible materials: Strong oxidising agents, Strong acids, epoxy functional compounds

Hazardous decomposition products: Carbon monoxide, Carbon dioxide & Nitrogen oxides.

 

  1. Toxicological information

Information on toxicological effects

Acute toxicity:

LD/LC50 values that are relevant for classification:

90-72-2 2,4,6-tris(dimethylaminomethyl)phenol

Oral LD50 1670 mg/kg (rat)

Dermal LD50 1400 mg/kg (rabbit)

Primary irritant effect:

on the skin:

• Caustic effect on skin and mucous membranes.

• Irritant to skin and mucous membranes.

on the eye:

• Strong caustic effect.

• Irritating effect.

Sensitization: No sensitizing effects known.

Additional toxicological information:

• Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of

perforation of esophagus and stomach.

Carcinogenic categories

IARC (International Agency for Research on Cancer)

• Substance is not listed.

NTP (National Toxicology Program)

• Substance is not listed.

OSHA-Ca (Occupational Safety & Health Administration)

• Substance is not listed.

 

  1. Ecological information

Toxicity

Aquatic toxicity: No further relevant information available.

Persistence and degradability No further relevant information available.

Bioaccumulative potential No further relevant information available.

Mobility in soil No further relevant information available.

Additional ecological information:

General notes:

• Water hazard class 1 (Self-assessment): slightly hazardous for water

• Do not allow undiluted product or large quantities of it to reach ground water, water course

or sewage system.

• Must not reach bodies of water or drainage ditch undiluted or unneutralized.

Results of PBT and vPvB assessment

PBT: No data available

vPvB: No data available

Other adverse effects No further relevant information available.

  1. Disposal considerations

Waste treatment methods

Recommendation:

Must not be disposed of together with household garbage. Do not allow product to reach sewage

system.

Uncleanedpackagings:

Recommendation: Disposal must be made according to official regulations.

 

  1. Transport information

UN-Number

DOT, ADR, IMDG, IATA UN2735

UN proper shipping name

DOT, IMDG, IATA: AMINES, LIQUID, CORROSIVE, N.O.S. (2, 4, 6-tris (dimethylaminomethyl) phenol)

ADR 2735 AMINES, LIQUID, CORROSIVE, N.O.S. (2, 4, 6-tris (dimethylaminomethyl) phenol)

Transport hazard class (es)

DOT

Class 8 Corrosive substances

Label 8

ADR, IMDG, IATA

Class 8 Corrosive substances

Label 8

Packing group

DOT, ADR, IMDG, IATA III

Environmental hazards:

Marine pollutant: No

Special precautions for user Warning: Corrosive substances

EMS Number: F-A,S-B

Segregation groups Alkalis

Transport in bulk according to Annex II of

MARPOL73/78 and the IBC Code Not applicable.

UN “Model Regulation”: UN2735, AMINES, LIQUID, CORROSIVE, N.O.S. (2, 4, 6 tris

(Dimethylaminomethyl) phenol), 8, III

 

  1. Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Sara

Section 355 (extremely hazardous substances):

• Substance is not listed.

Section 313 (Specific toxic chemical listings):

• Substance is not listed.

TSCA (Toxic Substances Control Act):

• Substance is listed.

Proposition 65

Chemicals known to cause cancer:

• Substance is not listed.

Chemicals known to cause reproductive toxicity for females:

• Substance is not listed.

Chemicals known to cause reproductive toxicity for males:

• Substance is not listed.

Chemicals known to cause developmental toxicity:

• Substance is not listed.

Carcinogenic categories

EPA (Environmental Protection Agency)

• Substance is not listed.

TLV (Threshold Limit Value established by ACGIH)

• Substance is not listed.

NIOSH-Ca (National Institute for Occupational Safety and Health)

• Substance is not listed.

GHS label elements

• GHS label elements

• The substance is classified and labeled according to the Globally Harmonized System (GHS).

Hazard pictograms

GHS07

Signal word Warning

Hazard-determining components of labeling:

• 2,4,6-tris(dimethylaminomethyl)phenol

Hazard statements

• H302 Harmful if swallowed.

• H315 Causes skin irritation.

• H319 Causes serious eye irritation.

  • Precautionary statements

• P101 If medical advice is needed, have product container or label at hand.

• P102 Keep out of reach of children.

• P103 Read label before use.

• P280 Wear protective gloves.

• P280 Wear eye protection / face protection.

• P264 Wash thoroughly after handling.

• P270 Do not eat, drink or smoke when using this product.

• P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy to do. Continue rinsing.

• P321 Specific treatment (see on this label).

• P301+P312 If swallowed: Call a poison center/doctor if you feel unwell.

• P332+P313 If skin irritation occurs: Get medical advice/attention.

• P337+P313 If eye irritation persists: Get medical advice/attention.

• P330 Rinse mouth.

• P302+P352 If on skin: Wash with plenty of water.

• P362+P364 Take off contaminated clothing and wash it before reuse.

• P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

 

  1. Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee

for any specific product features and shall not establish a legally valid contractual relationship.

Department issuing SDS: Corporate Product Safety & REACH

Contact:

EMAIL:

Abbreviations and acronyms:

RID:Règlement international concernant le transport des marchandisesdangereuses par chemin de

fer (Regulations Concerning the International

Transport of Dangerous Goods by Rail)

ICAO: International Civil Aviation Organisation

ADR: Accord européensur le transport des marchandisesdangereuses par Route (European

Agreement concerning the International Carriage of Dangerous Goods by Road)

IMDG: International Maritime Code for Dangerous Goods

DOT: US Department of Transportation

IATA: International Air Transport Association

ACGIH: American Conference of Governmental Industrial Hygienists

EINECS: European Inventory of Existing Commercial Chemical Substances

CAS: Chemical Abstracts Service (division of the American Chemical Society)

NFPA: National Fire Protection Association (USA)

HMIS: Hazardous Materials Identification System (USA)

Acute Tox. 4: Acute toxicity, Hazard Category 4

Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2

Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A