- Identification
Product identifier
Trade name: ESSPY-PHK-100
Relevant identified uses of the substance or mixture and uses advised against Hardener (Curing
agent) for epoxy resins.
Application of the substance / the mixture Curing agent for epoxy resin useful for coating & paint
applications.
- Hazard(s) identification
Classification of the substance or mixture
GHS05 Corrosion
Eye Dam. 1 H318 Causes serious eye damage.
GHS07
Skin Irrit. 2 H315 Causes skin irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Label elements
GHS label elements The product is classified and labeled according to the Globally Harmonized
System (GHS).
Hazard pictograms
GHS05 GHS07
Signal word Danger
Hazard-determining components of labeling:
2,2′-iminodiethylamine
Hazard statements
H315 Causes skin irritation.
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P280 Wear protective gloves.
P280 Wear eye protection / face protection.
P264 Wash thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of the workplace.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy todo. Continue rinsing.
P310 Immediately call a poison center/doctor.
P321 Specific treatment (see on this label).
P363 Wash contaminated clothing before reuse.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P302+P352 If on skin: Wash with plenty of water.
P362+P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Classification system:
NFPA ratings (scale 0 – 4
Health = 0
Fire = 1
Reactivity = 0
HMIS-ratings (scale 0 – 4)H
Health = 0
Fire = 1
Reactivity = 0
Other hazards
Results of PBT and vPvB assessment
PBT: No data available
vPvB: No data available
- Composition/information on ingredients
Chemical characterization: Mixtures
Description: Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
[68413-29-6] Alkylated polyamine adduct 90-97.5%
111-40-0 2,2′-iminodiethylamine
Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317
2.5-10%
SVHC Does not fall under SVHC substance
- First-aid measures
Description of first aid measures
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing: If symptoms persist consult doctor.
Most important symptoms and effects, both acute and delayed No further relevant information
available.
Indication of any immediate medical attention and special treatment needed No further relevant
information available.
- Fire-fighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant
foam.
Special hazards arising from the substance or mixture Oixdes of Carbon & nitrogen.
Advice for firefighters
Fire fighters to wear self-contained breathing apparatus and suitable protective
clothing if risk of exposure to vapour or products of combustion.
Protective equipment: Wear self-contained respiratory protective device.
- Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective clothing.
Particular danger of slipping on leaked/spilled product.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions: Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders,
sawdust).
Ensure adequate ventilation.
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
- Handling and storage
Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires: No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles: Store in a cool location.
Information about storage in one common storage facility:
Do not store together with reducing agents, heavy-metal compounds, acids and alkalis.
Further information about storage conditions: Store in cool, dry conditions in well sealed
receptacles.
Specific end use(s) Hardener (Curing agent) for coating & paint applications.
- Exposure controls/personal protection
Additional information about design of technical systems: No further data; see item 7.
Control parameters
Components with limit values that require monitoring at the workplace:
111-40-0 2,2′-iminodiethylamine
REL Long-term value: 4 mg/m³, 1 ppm
Skin
TLV Long-term value: 4.2 mg/m³, 1 ppm
Skin
Additional information: The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Breathing equipment:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or
longer exposure use respiratory
protective device that is independent of circulating air.
Protection of hands:rotective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/ the chemicalmixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies frommanufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material cannot be calculated in advance and has therefore
to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and
has to be observed.
Eye protection: Goggles recommended during refilling.
- Physical and chemical properties
Information on basic physical and chemical properties
General Information
Form: Viscous Liquid
Color: Yellow brown liquid
Odor: Characteristic
Odour threshold: Not determined.
pH-value: Alkaline
Change in condition
Melting point/Melting range: No data available
Boiling point/Boiling range: 207 °C (405 °F)
Flash point: 97 °C (207 °F)
Flammability (solid, gaseous): Not applicable.
Ignition temperature: No data available
Decomposition temperature: No data available
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:
Lower: No data available
Upper: No data available
Vapor pressure: No data available
Density at 20 °C (68 °F): 0.98 g/cm³ (8.178 lbs/gal)
Solubility in / Miscibility with
Water: Not miscible or difficult to mix.
Partition coefficient (n-octanol/water): No data available
Viscosity:
Dynamic at 25 °C (77 °F): 2000-5000 mPas (ASTM D 2196)
Solvent content:
Organic solvents: 0.0 %
Solids content: 95 %
Other information No further relevant information available.
- Stability and reactivity
Reactivity
Chemical stability
Thermal decomposition / conditions to be avoided: No decomposition if used according to
specifications.
Possibility of hazardous reactions Reacts with epoxy functional compounds with exothermic
reaction liberation of fumes.
Conditions to avoid No further relevant information available.
Incompatible materials: Strong oxidising agents, Strong acids, epoxy functional compounds
Hazardous decomposition products: No dangerous decomposition products known.
- Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values that are relevant for classification:
LD50 Oral Rat > 2,000 mg/kg
LD50 Skin Rabbit > 2,000 mg/kg
Primary irritant effect:
on the skin: No irritant effect.
on the eye: No irritating effect.
Sensitization: Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for
preparations:
Irritant
Carcinogenic categories
IARC (International Agency for Research on Cancer)
None of the ingredients is listed.
NTP (National Toxicology Program)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.
- Ecological information
Toxicity
Aquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Water hazard class 2 (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Results of PBT and vPvB assessment
PBT: No data available
vPvB: No data available
Other adverse effects No further relevant information available.
- Disposal considerations
Waste treatment methods
Recommendation: Must not be disposed of together with household garbage. Do not allow product
to reach sewage system.
40.0
Uncleanedpackagings:
Recommendation: Disposal must be made according to official regulations.
- Transport information
UN-Number
DOT, ADR, ADN, IMDG, IATA Void
UN proper shipping name
DOT, ADR, ADN, IMDG, IATA Void
Transport hazard class(es)
DOT, ADR, ADN, IMDG, IATA
Class Void
Packing group
DOT, ADR, IMDG, IATA Void
Environmental hazards: Not applicable.
Marine pollutant: NO
Special precautions for user Not applicable.
Transport in bulk according to Annex II of MARPOL73/78
and the IBC Code Not applicable.
UN “Model Regulation”: Not regulated by any mode of transport.
- Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
Sara
Section 355 (extremely hazardous substances):
None of the ingredients is listed.
Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All ingredients are listed.
Proposition 65
Chemicals known to cause cancer:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for females:
None of the ingredients is listed.
Chemicals known to cause reproductive toxicity for males:
None of the ingredients is listed.
Chemicals known to cause developmental toxicity:
None of the ingredients is listed.
Carcinogenic categories
PA (Environmental Protection Agency)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
GHS label elements The product is classified and labeled according to the Globally Harmonized System
(GHS).
Hazard pictograms
GHS05 GHS07
Signal word Danger
Hazard-determining components of labeling:
2,2′-iminodiethylamine
Hazard statements
H315 Causes skin irritation.
H318 Causes serious eye damage.
H317 May cause an allergic skin reaction.
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P261 Avoid breathing dust/fume/gas/mist/vapors/spray
P280 Wear protective gloves.
P280 Wear eye protection / face protection.
P264 Wash thoroughly after handling.
P272 Contaminated work clothing must not be allowed out of the workplace.
P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy todo. Continue rinsing.
P310 Immediately call a poison center/doctor.
P321 Specific treatment (see on this label).
P363 Wash contaminated clothing before reuse.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P302+P352 If on skin: Wash with plenty of water.
P362+P364 Take off contaminated clothing and wash it before reuse.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
- Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee
for any specific product features and shall not establish a legally valid contractual relationship.
Department issuing SDS: Corporate Product Safety & REACH
Contact:+91-0261-2279872
E-Mail:
Abbreviations and acronyms
RID:Règlement international concernant le transport des marchandisesdangereuses par chemin de
fer (Regulations Concerning the InternationalTransport of Dangerous Goods by Rail)
IATA-DGR: Dangerous Goods Regulations by the “International Air Transport Association” (IATA)
ICAO: International Civil Aviation Organisation
ICAO-TI: Technical Instructions by the “International Civil Aviation Organisation” (ICAO)
ADR: Accord européensur le transport des marchandisesdangereuses par Route (European
Agreement concerning the International Carriage ofDangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
DOT: US Department of Transportation
IATA: International Air Transport Association
ACGIH: American Conference of Governmental Industrial Hygienists
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
NFPA: National Fire Protection Association (USA)
HMIS: Hazardous Materials Identification System (USA)
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1
Skin Sens. 1:Sensitisation – Skin, Hazard Category 1