ESSPY EXA-450

Identification of substance PRODUTS DETAILS:  Trade name: ESSPY EXA-450 Application of the substance / the preparation Curing agent for epoxy resin   Composition/Data on components Chemical characterization Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: 111-40-0 2, 2’-iminodiethylamine C, Xn; R 21/22-34-43 Danger: 3.2/1B Warning: 3.1.O/4, 3.1.D/4, 3.4.S/1 50-70% 80-05-7 bisphenol A Repr. Cat. 3; Xn, Xi; R 37-41-43-62-52 Danger: 3.3/1 Warning: 3.7/2; 3.4.S/1, 3.8/3 25-45%   Hazards identification Hazard description: C Corrosive Information pertaining to particular dangers for man and environment: The product has to be labelled due to the calculation procedure of international guidelines. R 21/22 Harmful in contact with skin and if swallowed. R 34 Causes burns. R 37 Irritating to respiratory system. R 43 May cause sensitisation by skin contact. R 62 Possible risk of impaired fertility. R 52 Harmful to aquatic organisms. Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon From company and literature data. NFPA ratings (scale 0 – 4) 3 1 0 Health = 3 Fire = 1 Reactivity = 0 HMIS-ratings (scale 0 – 4) HEALTH FIRE REACTIVITY *3 1 0 Health = *3 Fire = 1 Reactivity = 0 GHS label elements Danger H314 – Causes severe skin burns and eye damage. Warning H361 – Suspected of damaging fertility or the unborn child. Warning H302 – Harmful if swallowed. H312 – Harmful in contact with skin. H317 – May cause an allergic skin reaction. H335 – May cause respiratory irritation. H402 – Harmful to aquatic life. Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P261 Avoid breathing dust/fume/gas/mist/vapours/spray. P264 Wash thoroughly after handling. P270 Do no eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P281 Use personal protective equipment as required. Response: P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P302+P352 IF ON SKIN: Wash with plenty of soap and water. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P310 Immediately call a POISON CENTER or doctor/physician. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P321 Specific treatment (see on this label). P322 Specific measures (see on this label). P330 Rinse mouth. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P363 Wash contaminated clothing before reuse. Storage: P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. Disposal: P501 Dispose of contents/container in accordance with local/regional/national/international regulations.   First aid measures General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. After inhalation: Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Immediately call a doctor. Drink copious amounts of water and provide fresh air. Immediately call a doctor.   Fire fighting measures Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Protective equipment: Wear fully protective suit.   Accidental release measures Person-related safety precautions: Wear protective equipment. Keep unprotected persons away. Measures for environmental protection: Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Use neutralizing agent. Dispose contaminated material as waste according to item 13. Ensure adequate ventilation.   Handling and storage Handling: Information for safe handling: Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. Information about protection against explosions and fires: No special measures required. Storage: Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep receptacle tightly sealed.   Exposure controls and personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: 111-40-0 2,2′-iminodiethylamine REL TLV 4 mg/m³, 1 ppm Skin 4.2 mg/m³, 1 ppm Skin Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment: General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. Breathing equipment: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on …

ESSPY-PHK-100

Identification Product identifier Trade name: ESSPY-PHK-100 Relevant identified uses of the substance or mixture and uses advised against Hardener (Curing agent) for epoxy resins. Application of the substance / the mixture Curing agent for epoxy resin useful for coating & paint applications.   Hazard(s) identification Classification of the substance or mixture GHS05 Corrosion • Eye Dam. 1 H318 Causes serious eye damage. GHS07 • Skin Irrit. 2 H315 Causes skin irritation. • Skin Sens. 1 H317 May cause an allergic skin reaction. Label elements GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS05 GHS07 Signal word Danger Hazard-determining components of labeling: • 2,2′-iminodiethylamine Hazard statements • H315 Causes skin irritation. • H318 Causes serious eye damage. • H317 May cause an allergic skin reaction. Precautionary statements • P101 If medical advice is needed, have product container or label at hand. • P102 Keep out of reach of children. • P103 Read label before use. • P261 Avoid breathing dust/fume/gas/mist/vapors/spray • P280 Wear protective gloves. • P280 Wear eye protection / face protection. • P264 Wash thoroughly after handling. • P272 Contaminated work clothing must not be allowed out of the workplace. • P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing. • P310 Immediately call a poison center/doctor. • P321 Specific treatment (see on this label). • P363 Wash contaminated clothing before reuse. • P333+P313 If skin irritation or rash occurs: Get medical advice/attention. • P302+P352 If on skin: Wash with plenty of water. • P362+P364 Take off contaminated clothing and wash it before reuse. • P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Classification system: NFPA ratings (scale 0 – 4 • Health = 0 • Fire = 1 • Reactivity = 0 HMIS-ratings (scale 0 – 4)H • Health = 0 • Fire = 1 • Reactivity = 0 Other hazards Results of PBT and vPvB assessment PBT: No data available vPvB: No data available   Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: [68413-29-6] Alkylated polyamine adduct 90-97.5% 111-40-0 2,2′-iminodiethylamine Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317 2.5-10% SVHC Does not fall under SVHC substance   First-aid measures Description of first aid measures After inhalation: • Supply fresh air and to be sure call for a doctor. • In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available.   Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture Oixdes of Carbon & nitrogen. Advice for firefighters • Fire fighters to wear self-contained breathing apparatus and suitable protective • clothing if risk of exposure to vapour or products of combustion. Protective equipment: Wear self-contained respiratory protective device.   Accidental release measures Personal precautions, protective equipment and emergency procedures • Wear protective clothing. • Particular danger of slipping on leaked/spilled product. • Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: • Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). • Ensure adequate ventilation. Reference to other sections • See Section 7 for information on safe handling. • See Section 8 for information on personal protection equipment. • See Section 13 for disposal information.   Handling and storage Precautions for safe handling • Ensure good ventilation/exhaustion at the workplace. • Prevent formation of aerosols. Information about protection against explosions and fires: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: • Do not store together with reducing agents, heavy-metal compounds, acids and alkalis. Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. Specific end use(s) Hardener (Curing agent) for coating & paint applications.   Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: 111-40-0 2,2′-iminodiethylamine REL Long-term value: 4 mg/m³, 1 ppm Skin TLV Long-term value: 4.2 mg/m³, 1 ppm Skin Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: • Immediately remove all soiled and contaminated clothing. • Wash hands before breaks and at the end of work. Breathing equipment: • In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory • protective device that is independent of circulating air. Protection of hands:rotective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemicalmixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies frommanufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time has …

ESSPY-PHK-104

Identification Product identifier Trade name: ESSPY-PHK-104 Relevant identified uses of the substance or mixture and uses advised against Hardener (Curing agent) for epoxy resins. Application of the substance / the mixture Curing agent for epoxy resin useful for coating & paint applications.     Hazard(s) identification Classification of the substance or mixture GHS05 Corrosion • Eye Dam. 1 H318 Causes serious eye damage. GHS07 • Skin Irrit. 2 H315 Causes skin irritation. • Skin Sens. 1 H317 May cause an allergic skin reaction. Label elements GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS05 GHS07 Signal word Danger Hazard-determining components of labeling: • 2,2′-iminodiethylamine Hazard statements • H315 Causes skin irritation. • H318 Causes serious eye damage. • H317 May cause an allergic skin reaction. Precautionary statements • P101 If medical advice is needed, have product container or label at hand. • P102 Keep out of reach of children. • P103 Read label before use. • P261 Avoid breathing dust/fume/gas/mist/vapors/spray • P280 Wear protective gloves. • P280 Wear eye protection / face protection. • P264 Wash thoroughly after handling. • P272 Contaminated work clothing must not be allowed out of the workplace. • P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing. • P310 Immediately call a poison center/doctor. • P321 Specific treatment (see on this label). • P363 Wash contaminated clothing before reuse. • P333+P313 If skin irritation or rash occurs: Get medical advice/attention. • P302+P352 If on skin: Wash with plenty of water. • P362+P364 Take off contaminated clothing and wash it before reuse. • P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Classification system: NFPA ratings (scale 0 – 4 • Health = 0 • Fire = 1 • Reactivity = 0 HMIS-ratings (scale 0 – 4)H • Health = 0 • Fire = 1 • Reactivity = 0 Other hazards Results of PBT and vPvB assessment PBT: No data available vPvB: No data available   Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: [68413-29-6] Alkylated polyamine adduct 90-97.5% 111-40-0 2,2′-iminodiethylamine Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317 2.5-10% SVHC Does not fall under SVHC substance   First-aid measures Description of first aid measures After inhalation: • Supply fresh air and to be sure call for a doctor. • In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available.   Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture Oixdes of Carbon & nitrogen. Advice for firefighters • Fire fighters to wear self-contained breathing apparatus and suitable protective • clothing if risk of exposure to vapour or products of combustion. Protective equipment: Wear self-contained respiratory protective device.   Accidental release measures Personal precautions, protective equipment and emergency procedures • Wear protective clothing. • Particular danger of slipping on leaked/spilled product. • Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: • Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). • Ensure adequate ventilation. Reference to other sections • See Section 7 for information on safe handling. • See Section 8 for information on personal protection equipment. • See Section 13 for disposal information.   Handling and storage Precautions for safe handling • Ensure good ventilation/exhaustion at the workplace. • Prevent formation of aerosols. Information about protection against explosions and fires: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: • Do not store together with reducing agents, heavy-metal compounds, acids and alkalis. Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. Specific end use(s) Hardener (Curing agent) for coating & paint applications.   Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: 111-40-0 2,2′-iminodiethylamine REL Long-term value: 4 mg/m³, 1 ppm Skin TLV Long-term value: 4.2 mg/m³, 1 ppm Skin Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: • Immediately remove all soiled and contaminated clothing. • Wash hands before breaks and at the end of work. Breathing equipment: • In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory • protective device that is independent of circulating air. Protection of hands:rotective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemicalmixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies frommanufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break through time …

ESSPY-PHK-104LV

Identification Product identifier Technical Data here Trade name: ESSPY-PHK-104LV Relevant identified uses of the substance or mixture and uses advised against Hardener (Curing agent) for epoxy resins. Application of the substance / the mixture Curing agent for epoxy resin useful for coating & paint applications.   Hazard(s) identification Classification of the substance or mixture GHS05 Corrosion • Eye Dam. 1 H318 Causes serious eye damage. GHS07 • Skin Irrit. 2 H315 Causes skin irritation. • Skin Sens. 1 H317 May cause an allergic skin reaction. Label elements GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). Hazard pictograms GHS05 GHS07 Signal word Danger Hazard-determining components of labeling: • 2,2′-iminodiethylamine Hazard statements • H315 Causes skin irritation. • H318 Causes serious eye damage. • H317 May cause an allergic skin reaction. Precautionary statements • P101 If medical advice is needed, have product container or label at hand. • P102 Keep out of reach of children. • P103 Read label before use. • P261 Avoid breathing dust/fume/gas/mist/vapors/spray • P280 Wear protective gloves. • P280 Wear eye protection / face protection. • P264 Wash thoroughly after handling. • P272 Contaminated work clothing must not be allowed out of the workplace. • P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing. • P310 Immediately call a poison center/doctor. • P321 Specific treatment (see on this label). • P363 Wash contaminated clothing before reuse. • P333+P313 If skin irritation or rash occurs: Get medical advice/attention. • P302+P352 If on skin: Wash with plenty of water. • P362+P364 Take off contaminated clothing and wash it before reuse. • P501 Dispose of contents/container in accordance with local/regional/national/international regulations. Classification system: NFPA ratings (scale 0 – 4 • Health = 0 • Fire = 1 • Reactivity = 0 HMIS-ratings (scale 0 – 4)H • Health = 0 • Fire = 1 • Reactivity = 0 Other hazards Results of PBT and vPvB assessment PBT: No data available vPvB: No data available   Composition/information on ingredients Chemical characterization: Mixtures Description: Mixture of the substances listed below with nonhazardous additions. Dangerous components: [68413-29-6] Alkylated polyamine adduct 90-97.5% 111-40-0 2,2′-iminodiethylamine Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317 2.5-10% SVHC Does not fall under SVHC substance   First-aid measures Description of first aid measures After inhalation: • Supply fresh air and to be sure call for a doctor. • In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately wash with water and soap and rinse thoroughly. After eye contact: Rinse opened eye for several minutes under running water. After swallowing: If symptoms persist consult doctor. Most important symptoms and effects, both acute and delayed No further relevant information available. Indication of any immediate medical attention and special treatment needed No further relevant information available.   Fire-fighting measures Extinguishing media Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. Special hazards arising from the substance or mixture Oixdes of Carbon & nitrogen. Advice for firefighters • Fire fighters to wear self-contained breathing apparatus and suitable protective • clothing if risk of exposure to vapour or products of combustion. Protective equipment: Wear self-contained respiratory protective device.   Accidental release measures Personal precautions, protective equipment and emergency procedures • Wear protective clothing. • Particular danger of slipping on leaked/spilled product. • Wear protective equipment. Keep unprotected persons away. Environmental precautions: Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: • Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). • Ensure adequate ventilation. Reference to other sections • See Section 7 for information on safe handling. • See Section 8 for information on personal protection equipment. • See Section 13 for disposal information.   Handling and storage Precautions for safe handling • Ensure good ventilation/exhaustion at the workplace. • Prevent formation of aerosols. Information about protection against explosions and fires: No special measures required. Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Store in a cool location. Information about storage in one common storage facility: • Do not store together with reducing agents, heavy-metal compounds, acids and alkalis. Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. Specific end use(s) Hardener (Curing agent) for coating & paint applications.   Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Control parameters Components with limit values that require monitoring at the workplace: 111-40-0 2,2′-iminodiethylamine REL Long-term value: 4 mg/m³, 1 ppm Skin TLV Long-term value: 4.2 mg/m³, 1 ppm Skin Additional information: The lists that were valid during the creation were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: • Immediately remove all soiled and contaminated clothing. • Wash hands before breaks and at the end of work. Breathing equipment: • In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory • protective device that is independent of circulating air. Protection of hands:rotective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemicalmixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies frommanufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material cannot be calculated in advance and has therefore to be checked prior to the application. Penetration time of glove material The exact break …