1. Identification

Product identifier

Trade name: ESSPY-PHK-104LV

Relevant identified uses of the substance or mixture and uses advised against Hardener (Curing

agent) for epoxy resins.

Application of the substance / the mixture Curing agent for epoxy resin useful for coating & paint

applications.

 

2. Hazard(s) identification

Classification of the substance or mixture

GHS05 Corrosion

• Eye Dam. 1 H318 Causes serious eye damage.

GHS07

• Skin Irrit. 2 H315 Causes skin irritation.

• Skin Sens. 1 H317 May cause an allergic skin reaction.

Label elements

GHS label elements The product is classified and labeled according to the Globally Harmonized

System (GHS).

Hazard pictograms

GHS05 GHS07

Signal word Danger

Hazard-determining components of labeling:

• 2,2′-iminodiethylamine

Hazard statements

• H315 Causes skin irritation.

• H318 Causes serious eye damage.

• H317 May cause an allergic skin reaction.

Precautionary statements

• P101 If medical advice is needed, have product container or label at hand.

• P102 Keep out of reach of children.

• P103 Read label before use.

• P261 Avoid breathing dust/fume/gas/mist/vapors/spray

• P280 Wear protective gloves.

• P280 Wear eye protection / face protection.

• P264 Wash thoroughly after handling.

• P272 Contaminated work clothing must not be allowed out of the workplace.

• P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove

contact lenses, if present and easy todo. Continue rinsing.

• P310 Immediately call a poison center/doctor.

• P321 Specific treatment (see on this label).

• P363 Wash contaminated clothing before reuse.

• P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

• P302+P352 If on skin: Wash with plenty of water.

• P362+P364 Take off contaminated clothing and wash it before reuse.

• P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

Classification system:

NFPA ratings (scale 0 – 4

• Health = 0

• Fire = 1

• Reactivity = 0

HMIS-ratings (scale 0 – 4)H

• Health = 0

• Fire = 1

• Reactivity = 0

Other hazards

Results of PBT and vPvB assessment

PBT: No data available

vPvB: No data available

 

3. Composition/information on ingredients

Chemical characterization: Mixtures

Description: Mixture of the substances listed below with nonhazardous additions.

Dangerous components:

[68413-29-6] Alkylated polyamine adduct 90-97.5%

111-40-0 2,2′-iminodiethylamine

Skin Corr. 1B, H314; Acute Tox. 4, H302; Acute Tox. 4, H312; Skin Sens. 1, H317

2.5-10%

SVHC Does not fall under SVHC substance

 

4. First-aid measures

Description of first aid measures

After inhalation:

• Supply fresh air and to be sure call for a doctor.

• In case of unconsciousness place patient stably in side position for transportation.

After skin contact: Immediately wash with water and soap and rinse thoroughly.

After eye contact: Rinse opened eye for several minutes under running water.

After swallowing: If symptoms persist consult doctor.

Most important symptoms and effects, both acute and delayed No further relevant information

available.

Indication of any immediate medical attention and special treatment needed No further relevant

information available.

 

5. Fire-fighting measures

Extinguishing media

Suitable extinguishing agents:

CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant

foam.

Special hazards arising from the substance or mixture Oixdes of Carbon & nitrogen.

Advice for firefighters

• Fire fighters to wear self-contained breathing apparatus and suitable protective

• clothing if risk of exposure to vapour or products of combustion.

Protective equipment: Wear self-contained respiratory protective device.

 

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures

• Wear protective clothing.

• Particular danger of slipping on leaked/spilled product.

• Wear protective equipment. Keep unprotected persons away.

Environmental precautions: Do not allow to enter sewers/ surface or ground water.

Methods and material for containment and cleaning up:

• Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders,

sawdust).

• Ensure adequate ventilation.

Reference to other sections

• See Section 7 for information on safe handling.

• See Section 8 for information on personal protection equipment.

• See Section 13 for disposal information.

 

7. Handling and storage

Precautions for safe handling

• Ensure good ventilation/exhaustion at the workplace.

• Prevent formation of aerosols.

Information about protection against explosions and fires: No special measures required.

Conditions for safe storage, including any incompatibilities

Storage:

Requirements to be met by storerooms and receptacles: Store in a cool location.

Information about storage in one common storage facility:

• Do not store together with reducing agents, heavy-metal compounds, acids and alkalis.

Further information about storage conditions: Store in cool, dry conditions in well sealed

receptacles.

Specific end use(s) Hardener (Curing agent) for coating & paint applications.

 

8. Exposure controls/personal protection

Additional information about design of technical systems: No further data; see item 7.

Control parameters

Components with limit values that require monitoring at the workplace:

111-40-0 2,2′-iminodiethylamine

REL Long-term value: 4 mg/m³, 1 ppm

Skin

TLV Long-term value: 4.2 mg/m³, 1 ppm

Skin

Additional information: The lists that were valid during the creation were used as basis.

Exposure controls

Personal protective equipment:

General protective and hygienic measures:

• Immediately remove all soiled and contaminated clothing.

• Wash hands before breaks and at the end of work.

Breathing equipment:

• In case of brief exposure or low pollution use respiratory filter device. In case of intensive or

longer exposure use respiratory

• protective device that is independent of circulating air.

Protection of hands:rotective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the

preparation.

Due to missing tests no recommendation to the glove material can be given for the product/ the

preparation/ the chemicalmixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the

degradation

Material of gloves

The selection of the suitable gloves does not only depend on the material, but also on further marks

of quality and varies frommanufacturer to manufacturer. As the product is a preparation of several

substances, the resistance of the glove material cannot be calculated in advance and has therefore

to be checked prior to the application.

Penetration time of glove material

The exact break through time has to be found out by the manufacturer of the protective gloves and

has to be observed.

Eye protection: Goggles recommended during refilling.

 

9. Physical and chemical properties

Information on basic physical and chemical properties

General Information

Form: Viscous Liquid

Color: Yellow brown liquid

Odor: Characteristic

Odour threshold: Not determined.

pH-value: Alkaline

Change in condition

Melting point/Melting range: No data available

Boiling point/Boiling range: 207 °C (405 °F)

Flash point: 97 °C (207 °F)

Flammability (solid, gaseous): Not applicable.

Ignition temperature: No data available

Decomposition temperature: No data available

Auto igniting: Product is not selfigniting.

Danger of explosion: Product does not present an explosion hazard.

Explosion limits:

Lower: No data available

Upper: No data available

Vapor pressure: No data available

Density at 20 °C (68 °F): 0.98 g/cm³ (8.178 lbs/gal)

Solubility in / Miscibility with

Water: Not miscible or difficult to mix.

Partition coefficient (n-octanol/water): No data available

Viscosity:

Dynamic at 25 °C (77 °F): 15-30 Ps

Solvent content:

Organic solvents: 0.0 %

Solids content: 95 %

Other information No further relevant information available.

 

10. Stability and reactivity

Reactivity

Chemical stability

Thermal decomposition / conditions to be avoided: No decomposition if used according to

specifications.

Possibility of hazardous reactions Reacts with epoxy functional compounds with exothermic

reaction liberation of fumes.

Conditions to avoid No further relevant information available.

Incompatible materials: Strong oxidising agents, Strong acids, epoxy functional compounds

Hazardous decomposition products: No dangerous decomposition products known.

 

11. Toxicological information

Information on toxicological effects

Acute toxicity:

LD/LC50 values that are relevant for classification:

• LD50 Oral Rat > 2,000 mg/kg

• LD50 Skin Rabbit > 2,000 mg/kg

Primary irritant effect:

on the skin: No irritant effect.

on the eye: No irritating effect.

Sensitization: Sensitization possible through skin contact.

Additional toxicological information:

The product shows the following dangers according to internally approved calculation methods for

preparations:

Irritant

Carcinogenic categories

IARC (International Agency for Research on Cancer)

• None of the ingredients is listed.

NTP (National Toxicology Program)

• None of the ingredients is listed.

OSHA-Ca (Occupational Safety & Health Administration)

• None of the ingredients is listed.

 

12. Ecological information

Toxicity

Aquatic toxicity: No further relevant information available.

Persistence and degradability No further relevant information available.

Bioaccumulative potential No further relevant information available.

Mobility in soil No further relevant information available.

Additional ecological information:

General notes:

• Water hazard class 2 (Self-assessment): hazardous for water

• Do not allow product to reach ground water, water course or sewage system.

• Danger to drinking water if even small quantities leak into the ground.

Results of PBT and vPvB assessment

PBT: No data available

vPvB: No data available

Other adverse effects No further relevant information available.

 

13. Disposal considerations

Waste treatment methods

Recommendation: Must not be disposed of together with household garbage. Do not allow product

to reach sewage system.

40.0

Uncleanedpackagings:

Recommendation: Disposal must be made according to official regulations.

 

14. Transport information

UN-Number

DOT, ADR, ADN, IMDG, IATA Void

UN proper shipping name

DOT, ADR, ADN, IMDG, IATA Void

Transport hazard class(es)

DOT, ADR, ADN, IMDG, IATA

Class Void

Packing group

DOT, ADR, IMDG, IATA Void

Environmental hazards: Not applicable.

Marine pollutant: NO

Special precautions for user Not applicable.

Transport in bulk according to Annex II of MARPOL73/78

and the IBC Code Not applicable.

UN “Model Regulation”: Not regulated by any mode of transport.

 

15. Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or mixture

Sara

Section 355 (extremely hazardous substances):

• None of the ingredients is listed.

Section 313 (Specific toxic chemical listings):

• None of the ingredients is listed.

TSCA (Toxic Substances Control Act):

• All ingredients are listed.

Proposition 65

Chemicals known to cause cancer:

• None of the ingredients is listed.

Chemicals known to cause reproductive toxicity for females:

• None of the ingredients is listed.

Chemicals known to cause reproductive toxicity for males:

• None of the ingredients is listed.

Chemicals known to cause developmental toxicity:

• None of the ingredients is listed.

Carcinogenic categories

PA (Environmental Protection Agency)

• None of the ingredients is listed.

TLV (Threshold Limit Value established by ACGIH)

• None of the ingredients is listed.

NIOSH-Ca (National Institute for Occupational Safety and Health)

• None of the ingredients is listed.

GHS label elements The product is classified and labeled according to the Globally Harmonized System

(GHS).

Hazard pictograms

• GHS05 GHS07

Signal word Danger

Hazard-determining components of labeling:

2,2′-iminodiethylamine

Hazard statements

• H315 Causes skin irritation.

• H318 Causes serious eye damage.

• H317 May cause an allergic skin reaction.

Precautionary statements

• P101 If medical advice is needed, have product container or label at hand.

• P102 Keep out of reach of children.

• P103 Read label before use.

• P261 Avoid breathing dust/fume/gas/mist/vapors/spray

• P280 Wear protective gloves.

• P280 Wear eye protection / face protection.

• P264 Wash thoroughly after handling.

• P272 Contaminated work clothing must not be allowed out of the workplace.

• P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact

lenses, if present and easy todo. Continue rinsing.

• P310 Immediately call a poison center/doctor.

• P321 Specific treatment (see on this label).

• P363 Wash contaminated clothing before reuse.

• P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

• P302+P352 If on skin: Wash with plenty of water.

• P362+P364 Take off contaminated clothing and wash it before reuse.

• P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

 

16. Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee

for any specific product features and shall not establish a legally valid contractual relationship.

Department issuing SDS: Corporate Product Safety & REACH

Contact:+91-0261-2279872

E-Mail:

Abbreviations and acronyms

RID:Règlement international concernant le transport des marchandisesdangereuses par chemin de

fer (Regulations Concerning the InternationalTransport of Dangerous Goods by Rail)

IATA-DGR: Dangerous Goods Regulations by the “International Air Transport Association” (IATA)

ICAO: International Civil Aviation Organisation

ICAO-TI: Technical Instructions by the “International Civil Aviation Organisation” (ICAO)

ADR: Accord européensur le transport des marchandisesdangereuses par Route (European

Agreement concerning the International Carriage ofDangerous Goods by Road)

IMDG: International Maritime Code for Dangerous Goods

DOT: US Department of Transportation

IATA: International Air Transport Association

ACGIH: American Conference of Governmental Industrial Hygienists

EINECS: European Inventory of Existing Commercial Chemical Substances

ELINCS: European List of Notified Chemical Substances

CAS: Chemical Abstracts Service (division of the American Chemical Society)

NFPA: National Fire Protection Association (USA)

HMIS: Hazardous Materials Identification System (USA)

Acute Tox. 4: Acute toxicity, Hazard Category 4

Skin Corr. 1B: Skin corrosion/irritation, Hazard Category 1B

Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2

Eye Dam. 1: Serious eye damage/eye irritation, Hazard Category 1

Skin Sens. 1:Sensitisation – Skin, Hazard Category 1