ESSPY EXA-450

Identification of substance

PRODUTS DETAILS:

 Trade name: ESSPY EXA-450

Application of the substance / the preparation Curing agent for epoxy resin

Composition/Data on components

Chemical characterization
Description: Mixture of the substances listed below with nonhazardous additions.
Dangerous components:

111-40-0 2, 2’-iminodiethylamine C, Xn; R 21/22-34-43

Danger: 3.2/1B

Warning: 3.1.O/4, 3.1.D/4, 3.4.S/1

50-70%

80-05-7 bisphenol A Repr. Cat. 3; Xn, Xi; R 37-41-43-62-52

Danger: 3.3/1

Warning: 3.7/2; 3.4.S/1, 3.8/3

25-45%

Hazards identification

Hazard description:

C Corrosive

Information pertaining to particular dangers for man and environment:

The product has to be labelled due to the calculation procedure of international guidelines.

R 21/22 Harmful in contact with skin and if swallowed.

R 34 Causes burns.

R 37 Irritating to respiratory system.

R 43 May cause sensitisation by skin contact.

R 62 Possible risk of impaired fertility.

R 52 Harmful to aquatic organisms.

Classification system:

The classification was made according to the latest editions of international substances lists, and

expanded upon

From company and literature data.

NFPA ratings (scale 0 – 4)

Health = 3

Fire = 1

Reactivity = 0

HMIS-ratings (scale 0 – 4)

HEALTH

FIRE

REACTIVITY

Health = *3

Fire = 1

Reactivity = 0

GHS label elements

Danger

H314 – Causes severe skin burns and eye damage.

Warning

H361 – Suspected of damaging fertility or the unborn child.

Warning

H302 – Harmful if swallowed.

H312 – Harmful in contact with skin.

H317 – May cause an allergic skin reaction.

H335 – May cause respiratory irritation.

H402 – Harmful to aquatic life.

Prevention:

P201 Obtain special instructions before use.

P202 Do not handle until all safety precautions have been read and understood.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P261 Avoid breathing dust/fume/gas/mist/vapours/spray.

P264 Wash thoroughly after handling.

P270 Do no eat, drink or smoke when using this product.

P271 Use only outdoors or in a well-ventilated area.

P272 Contaminated work clothing should not be allowed out of the workplace.

P273 Avoid release to the environment.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P281 Use personal protective equipment as required.

Response:

P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.

Rinse skin

with water/shower.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for

breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact

lenses, if

present and easy to do. Continue rinsing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P310 Immediately call a POISON CENTER or doctor/physician.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment (see on this label).

P322 Specific measures (see on this label).

P330 Rinse mouth.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.

P363 Wash contaminated clothing before reuse.

Storage:

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Disposal:

P501 Dispose of contents/container in accordance with local/regional/national/international

regulations.

First aid measures

General information:

Immediately remove any clothing soiled by the product.

Symptoms of poisoning may even occur after several hours; therefore medical observation for at

least 48 hours

after the accident.

After inhalation:

Supply fresh air and to be sure call for a doctor.

In case of unconsciousness place patient stably in side position for transportation.

After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water. Then consult a

doctor.

After swallowing:

Immediately call a doctor.

Drink copious amounts of water and provide fresh air. Immediately call a doctor.

Fire fighting measures

Suitable extinguishing agents:

CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant

foam.

Protective equipment: Wear fully protective suit.

Accidental release measures

Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
Measures for environmental protection:

Do not allow product to reach sewage system or any water course.

Inform respective authorities in case of seepage into water course or sewage system.

Do not allow to enter sewers/ surface or ground water.

Measures for cleaning/collecting:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

Use neutralizing agent.

Dispose contaminated material as waste according to item 13.

Ensure adequate ventilation.

Handling and storage

Handling:
Information for safe handling:

Ensure good ventilation/exhaustion at the workplace.

Prevent formation of aerosols.

Information about protection against explosions and fires: No special measures required.
Storage:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Keep receptacle tightly sealed.

Exposure controls and personal protection

Additional information about design of technical systems: No further data; see item 7.
Components with limit values that require monitoring at the workplace:

111-40-0 2,2′-iminodiethylamine

REL

TLV

4 mg/m³, 1 ppm

Skin

4.2 mg/m³, 1 ppm

Skin

Additional information: The lists that were valid during the creation were used as basis.
Personal protective equipment:
General protective and hygienic measures:

Keep away from foodstuffs, beverages and feed.

Immediately remove all soiled and contaminated clothing.

Wash hands before breaks and at the end of work.

Avoid contact with the eyes and skin.

Breathing equipment:

In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer

exposure use

respiratory protective device that is independent of circulating air.

Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the

preparation.

Due to missing tests no recommendation to the glove material can be given for the product/ the

preparation/ the

chemical mixture.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the

degradation

Material of gloves

The selection of the suitable gloves does not only depend on the material, but also on further marks

of quality and

varies from manufacturer to manufacturer. As the product is a preparation of several substances,

the resistance of

the glove material can not be calculated in advance and has therefore to be checked prior to the

application.

Penetration time of glove material

The exact break through time has to be found out by the manufacturer of the protective gloves and

has to be

Eye protection:

Tightly sealed goggles

Physical and chemical properties

General Information

Form: Liquid

Color: Dark yellow

Odor: Amine-like

Change in condition

Melting point/Melting range: Undetermined.

Boiling point/Boiling range: 207°C (405°F)

Flash point: 97°C (207°F)
Ignition temperature: 325°C (617°F)
Auto igniting: Product is not selfigniting.
Danger of explosion: Product does not present an explosion hazard.
Explosion limits:

Lower: 1.0 Vol %

Upper: 10.0 Vol %

Vapor pressure at 20°C (68°F): 0.5 hPa
Density at 20°C (68°F): 1.09 g/cm³
Solubility in / Miscibility with

Water: Not miscible or difficult to mix.

pH-value: Alkaline
Viscosity:

Dynamic at 20°C (68°F): 400 mPas

Solvent content:

Organic solvents: 0.0 %

Solids content: 35.0 %

Stability and reactivity

Thermal decomposition / conditions to be avoided: No decomposition if used according to

specifications.

Materials to be avoided: Strong oxidising agents, Strong acids, epoxy functional compounds
Dangerous reactions Reacts with epoxy functional compounds with exothermic reaction liberation

of fumes.

Dangerous products of decomposition: No dangerous decomposition products known.

Toxicological information

Acute toxicity:
LD/LC50 values that are relevant for classification:

111-40-0 2,2′-iminodiethylamine

Oral LD50 1080 mg/kg (rat)

Dermal LD50 1090 mg/kg (rabbit)

80-05-7 bisphenol A

Oral LD50 3250 mg/kg (rat)

Dermal LD50 3000 mg/kg (rabbit)

Primary irritant effect:
on the skin: Caustic effect on skin and mucous membranes.
on the eye: Strong caustic effect.
Sensitization: Sensitization possible through skin contact.
Additional toxicological information:

The product shows the following dangers according to internally approved calculation methods for

preparations:

Harmful

Corrosive

Irritant

Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation

of esophagus

and stomach.

Ecological information

Ecotoxical effects:
Remark: Harmful to fish
General notes:

Water hazard class 2 (Self-assessment): hazardous for water

Do not allow product to reach ground water, water course or sewage system.

Must not reach bodies of water or drainage ditch undiluted or unneutralized.

Danger to drinking water if even small quantities leak into the ground.

Harmful to aquatic organisms

Disposal considerations

Product:
Recommendation:

Must not be disposed of together with household garbage. Do not allow product to reach sewage

system.

Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.

Transport information

DOT regulations:
Hazard class: 8
Identification number: UN2735
Packing group: II
Proper shipping name (technical name): AMINES, LIQUID, CORROSIVE, N.O.S.

(DIETHYLENETRIAMINE)

Label 8
Land transport ADR/RID (cross-border):
ADR/RID class: 8 Corrosive substances
Danger code (Kemler): 80
UN-Number: 2735
Packaging group: II
Label: 8
Description of goods: 2 7 3 5 A M I N E S , L I Q U I D , C O R R O S I V E , N . O . S .

(DIETHYLENETRIAMINE)

Maritime transport IMDG:
IMDG Class: 8
UN Number: 2735
Label 8
Packaging group: II
EMS Number: F-A,S-B
Marine pollutant: NO
Propper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (DIETHYLENETRIAMINE)
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: 8
UN/ID Number: 2735
Label 8
Packaging group: II
Proper shipping name: AMINES, LIQUID, CORROSIVE, N.O.S. (DIETHYLENETRIAMINE)
UN “Model Regulation”: UN2735, AMINES, LIQUID, CORROSIVE, N.O.S., 8, II

Regulations

Sara
Section 355 (extremely hazardous substances):